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2-Meth-oxy-anilinium trichlorido-stannate(II).

ABSTRACT: The title compound, (C7H10NO)[SnCl3], is a new compound with non-linear optical (NLO) properties. The structure is pseudocentrosymmetric; the absence of an inversion centre was proved by the Kurtz and Perry method showing a significant second harmonic generation (SHG) signal about ten times lower than that from potassium dihydrogenphosphate. The crystal structure exhibits alternating organic and inorganic layers parallel to the ab plane, which are stabilized by inter-molecular N-H?Cl inter-actions.

SUBMITTER: Karoui S

PROVIDER: S-EPMC3629472 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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2-Meth-oxy-anilinium trichlorido-stannate(II).

Karoui Sahel S Kamoun Slaheddine S Michaud François F

Acta crystallographica. Section E, Structure reports online 20130306 Pt 4

The title compound, (C7H10NO)[SnCl3], is a new compound with non-linear optical (NLO) properties. The structure is pseudocentrosymmetric; the absence of an inversion centre was proved by the Kurtz and Perry method showing a significant second harmonic generation (SHG) signal about ten times lower than that from potassium dihydrogenphosphate. The crystal structure exhibits alternating organic and inorganic layers parallel to the ab plane, which are stabilized by inter-molecular N-H⋯Cl inter-actio ...[more]

PMID: 23633990

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