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Tris(aceto-nitrile-?N)dichlorido(tri-phenyl-phosphane-?P)ruthenium(II) aceto-nitrile monosolvate.

ABSTRACT: In the title complex, [RuCl2(CH3CN)3(C18H15P)]·CH3CN, the coordination geometry of the Ru(II) atom is distorted octa-hedral, defined by one P atom from a tri-phenyl-phosphane ligand, three N atoms from three aceto-nitrile ligands and two Cl atoms. The three acetronitile ligands linearly bind to the Ru(II) atom, with Ru-N-C angles of 172.6?(2), 179.9?(2) and 171.4?(2)°.

SUBMITTER: Yin XF

PROVIDER: S-EPMC3684898 | biostudies-literature | 2013 Jun

REPOSITORIES: biostudies-literature

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Tris(aceto-nitrile-κN)dichlorido(tri-phenyl-phosphane-κP)ruthenium(II) aceto-nitrile monosolvate.

Yin Xiao-Feng XF Qin Yi Y Shi Hua-Tian HT Chen Qun Q Zhang Qian-Feng QF

Acta crystallographica. Section E, Structure reports online 20130525 Pt 6

In the title complex, [RuCl2(CH3CN)3(C18H15P)]·CH3CN, the coordination geometry of the Ru(II) atom is distorted octa-hedral, defined by one P atom from a tri-phenyl-phosphane ligand, three N atoms from three aceto-nitrile ligands and two Cl atoms. The three acetronitile ligands linearly bind to the Ru(II) atom, with Ru-N-C angles of 172.6 (2), 179.9 (2) and 171.4 (2)°. ...[more]

PMID: 23795000

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