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Dichlorido(3-phenyl-indenyl-idene)bis-(triphenyl-phosphane)ruthenium(II) tetra-hydro-furan disolvate.

ABSTRACT: The Ru(II) atom in the title compound, [RuCl(2)(C(15)H(10))(C(18)H(15)P)(2)]·2C(4)H(8)O, has a distorted square-pyramidal conformation. The P and Cl atoms are at the base of the pyramid and the Ru-C(indenyl-idene) bond is in the axial position. The two Cl ligands and the two phosphane ligands are in trans positions. The Cl-Ru-Cl and P-Ru-P angles are 157.71?(2) and 166.83?(2)°, respectively. The two independent tetra-hydro-furan (THF) solvent mol-ecules are disordered. One THF mol-ecule was refined using a split-atom model. The second THF mol-ecule was accounted for by using program PLATON/SQUEEZE [Spek (2009 ?). Acta Cryst. D65, 148-155]. The molecular conformation shows three intramolecular C-H?Cl contacts and two C-H?? interactions while the crystal packing features an intermolecular C-H?Cl contact and two very weak intermolecular C-H?? contacts.

SUBMITTER: Bats JW

PROVIDER: S-EPMC3120390 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Dichlorido(3-phenyl-indenyl-idene)bis-(triphenyl-phosphane)ruthenium(II) tetra-hydro-furan disolvate.

Bats Jan W JW Pérez Gomes Jessica J Doppiu Angelino A Hashmi A Stephen K AS

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The Ru(II) atom in the title compound, [RuCl(2)(C(15)H(10))(C(18)H(15)P)(2)]·2C(4)H(8)O, has a distorted square-pyramidal conformation. The P and Cl atoms are at the base of the pyramid and the Ru-C(indenyl-idene) bond is in the axial position. The two Cl ligands and the two phosphane ligands are in trans positions. The Cl-Ru-Cl and P-Ru-P angles are 157.71 (2) and 166.83 (2)°, respectively. The two independent tetra-hydro-furan (THF) solvent mol-ecules are disordered. One THF mol-ecule was refi ...[more]

PMID: 21754621

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