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Palladium-catalyzed oxidative regio- and diastereoselective diarylating carbocyclization of dienynes.

ABSTRACT: Transmetallation: A highly regio- and diastereoselective carbocyclization involving a palladium-catalyzed 1,2-addition of two carbon atoms across a conjugated diene has been developed (see scheme). The reaction is performed with dienynes and an oxygen tether containing a terminal or internal triple bond.

SUBMITTER: Jiang M

PROVIDER: S-EPMC3743347 | biostudies-literature | 2013 May

REPOSITORIES: biostudies-literature

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Palladium-catalyzed oxidative regio- and diastereoselective diarylating carbocyclization of dienynes.

Jiang Min M Bäckvall Jan-E JE

Chemistry (Weinheim an der Bergstrasse, Germany) 20130409 21

Transmetallation: A highly regio- and diastereoselective carbocyclization involving a palladium-catalyzed 1,2-addition of two carbon atoms across a conjugated diene has been developed (see scheme). The reaction is performed with dienynes and an oxygen tether containing a terminal or internal triple bond. ...[more]

PMID: 23576471

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