Ontology highlight
ABSTRACT:
SUBMITTER: Liu J
PROVIDER: S-EPMC6471031 | biostudies-literature | 2018 Dec
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20181120 51
Herein, we communicate a selective and efficient protocol for oxidative arylating carbocyclization of enallenynes using O<sub>2</sub> as the oxidant. The key to success for this aerobic transformation is the application of a specific electron transfer mediator (ETM), a bifunctional catalyst consisting of a metal-macrocycle and quinone moieties. This catalyst significantly facilitates the reoxidation of Pd<sup>0</sup> to Pd<sup>II</sup> under atmospheric pressure of O<sub>2</sub> . Diverse functi ...[more]