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Gold(I)-catalysed one-pot synthesis of chromans using allylic alcohols and phenols.

ABSTRACT: A gold(I)-catalysed reaction of allylic alcohols and phenols produces chromans regioselectively via a one-pot Friedel-Crafts allylation/intramolecular hydroalkoxylation sequence. The reaction is mild, practical and tolerant of a wide variety of substituents on the phenol.

SUBMITTER: Coutant E 

PROVIDER: S-EPMC3778418 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Gold(I)-catalysed one-pot synthesis of chromans using allylic alcohols and phenols.

Coutant Eloi E   Young Paul C PC   Barker Graeme G   Lee Ai-Lan AL  

Beilstein journal of organic chemistry 20130904

A gold(I)-catalysed reaction of allylic alcohols and phenols produces chromans regioselectively via a one-pot Friedel-Crafts allylation/intramolecular hydroalkoxylation sequence. The reaction is mild, practical and tolerant of a wide variety of substituents on the phenol. ...[more]

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