Dataset Information
Regioselective 1,4-trifluoromethylation of ?,?-unsaturated ketones via a S-(trifluoromethyl)diphenylsulfonium salts/copper system.
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ABSTRACT:
SUBMITTER: Okusu S
PROVIDER: S-EPMC3817478 | biostudies-literature | 2013
REPOSITORIES: biostudies-literature
Publications
Regioselective 1,4-trifluoromethylation of α,β-unsaturated ketones via a S-(trifluoromethyl)diphenylsulfonium salts/copper system.
Beilstein journal of organic chemistry 20131023
Regioselective conjugate 1,4-trifluoromethylation of α,β-unsaturated ketones by the use of shelf-stable electrophilic trifluoromethylating reagents, S-(trifluoromethyl)diphenylsulfonium salts and copper under mild conditions is described. A wide range of acyclic aryl-aryl-enones and aryl-alkyl-enones were converted into β-trifluoromethylated ketones in low to moderate yields. ...[more]