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Bis(2-meth-oxy-benzyl-ammonium) di-aqua-bis-(di-hydrogen diphosphato-?(2) O,O')manganate(II) dihydrate.

ABSTRACT: The asymmetric unit of the title compound, (C8H12NO)2[Mn(H2P2O7)2(H2O)2]·2H2O, consists of half an Mn(II) complex anion, a 2-meth-oxy-benyl-ammonium cation and a solvent water mol-ecule. The Mn(II) complex anion lies across an inversion center, and has a slightly distorted octa-hedral coordination environment for the Mn(II) ion, formed by two bidentate dihydrogendiphosphate ligands and two water mol-ecules. In the crystal, the components are linked by O-H?O and N-H?O hydrogen bonds, forming layers parallel to (100). An intra-molecular N-H?O hydrogen bond is also observed.

SUBMITTER: Elboulali A

PROVIDER: S-EPMC3884241 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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Bis(2-meth-oxy-benzyl-ammonium) di-aqua-bis-(di-hydrogen diphosphato-κ(2) O,O')manganate(II) dihydrate.

Elboulali Adel A Akriche Samah S Rzaigui Mohamed M

Acta crystallographica. Section E, Structure reports online 20131002 Pt 11

The asymmetric unit of the title compound, (C8H12NO)2[Mn(H2P2O7)2(H2O)2]·2H2O, consists of half an Mn(II) complex anion, a 2-meth-oxy-benyl-ammonium cation and a solvent water mol-ecule. The Mn(II) complex anion lies across an inversion center, and has a slightly distorted octa-hedral coordination environment for the Mn(II) ion, formed by two bidentate dihydrogendiphosphate ligands and two water mol-ecules. In the crystal, the components are linked by O-H⋯O and N-H⋯O hydrogen bonds, forming laye ...[more]

PMID: 24454017

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