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Bis(tetra-butyl-ammonium) tetra-chlorido-manganate(II) di-chloro-methane disolvate.

ABSTRACT: The title compound, (C₁₆H₃₆N)₂[MnCl₄]·2CH₂Cl₂, is an ionic organic-inorganic hybride compound consisting of a tetra-butyl-ammonium cation and a tetra-chlorido-manganate(II) anion in a 2:1 stoichiometric ratio. The cation contains a central nitro-gen atom bonded to four n-butyl groups in a tetra-hedral arrangement, while the anion contains a central Mn^II atom tetra-hedrally coordinated by four chlorido ligands. It co-crystallized with two equivalents of di-chloro-methane solvent, CH₂Cl₂, to give the following empirical formula: [(C₄H₉)₄N]₂[MnCl₄]·(CH₂Cl₂)₂. The crystal structure is mainly stabilized by Coulombic inter-actions.

SUBMITTER: Hay MT

PROVIDER: S-EPMC10626607 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature

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Bis(tetra-butyl-ammonium) tetra-chlorido-manganate(II) di-chloro-methane disolvate.

Hay Michael T MT Yennawar Hemant P HP

IUCrData 20230714 Pt 7

The title compound, (C16H36N)2[MnCl4]·2CH2Cl2, is an ionic organic-inorganic hybride compound consisting of a tetra-butyl-ammonium cation and a tetra-chlorido-manganate(II) anion in a 2:1 stoichiometric ratio. The cation contains a central nitro-gen atom bonded to four n-butyl groups in a tetra-hedral arrangement, while the anion contains a central MnII atom tetra-hedrally coordinated by four chlorido ligands. It ...[more]

PMID: 37937132

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