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Tris(cyclo-hexyl-ammonium) cis-di-chlorido-bis-(oxalato-?(2) O (1),O (2))stann-ate(IV) chloride monohydrate.

ABSTRACT: The crystal structure of the title compound, (C6H14N)3[Sn(C2O4)2Cl2]Cl·H2O, contains three cyclo-hexyl-ammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water mol-ecule. The cyclo-hexyl-ammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octa-hedrally to the central Sn(IV) atom. The cohesion of the mol-ecular entities is ensured by the formation of N-H?O, O-H?O, O-H?Cl and N-H?Cl inter-actions involving cations, anions and the lattice water mol-ecule, giving rise to a layer-like arrangement parallel to (010).

SUBMITTER: Sarr M 

PROVIDER: S-EPMC3884246 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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Tris(cyclo-hexyl-ammonium) cis-di-chlorido-bis-(oxalato-κ(2) O (1),O (2))stann-ate(IV) chloride monohydrate.

Sarr Modou M   Diallo Waly W   Diasse-Sarr Aminata A   Plasseraud Laurent L   Cattey Hélène H  

Acta crystallographica. Section E, Structure reports online 20131005 Pt 11

The crystal structure of the title compound, (C6H14N)3[Sn(C2O4)2Cl2]Cl·H2O, contains three cyclo-hexyl-ammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water mol-ecule. The cyclo-hexyl-ammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octa-hedrally to the central Sn(IV) atom. The cohesion of the mol-ecular entities is ensured by the formation of N-H⋯O, O-H⋯O, O  ...[more]

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