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4-Methyl-N-(4-nitro-benzyl-idene)piperazin-1-amine.

ABSTRACT: In the title compound, C12H16N4O2, the piperazine ring is in a slightly distorted chair conformation. In the mol-ecule, the mean plane of the nitro group is twisted by 8.0?(3)° from that of the benzene ring. Also, the mean plane of the 2-nitro-benzyl ring is twisted slightly from that of the piperazine ring, with an N-N=C-C torsion angle of -176.24?(11)°. In the crystal, pairs of weak C-H?O inter-actions link the mol-ecules into dimers approximately along [010].

SUBMITTER: Kavitha CN

PROVIDER: S-EPMC3884341 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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4-Methyl-N-(4-nitro-benzyl-idene)piperazin-1-amine.

Kavitha Channappa N CN Jasinski Jerry P JP Anderson Brian J BJ Yathirajan H S HS Kaur Manpreet M

Acta crystallographica. Section E, Structure reports online 20131023 Pt 11

In the title compound, C12H16N4O2, the piperazine ring is in a slightly distorted chair conformation. In the mol-ecule, the mean plane of the nitro group is twisted by 8.0 (3)° from that of the benzene ring. Also, the mean plane of the 2-nitro-benzyl ring is twisted slightly from that of the piperazine ring, with an N-N=C-C torsion angle of -176.24 (11)°. In the crystal, pairs of weak C-H⋯O inter-actions link the mol-ecules into dimers approximately along [010]. ...[more]

PMID: 24454117

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