Ontology highlight
ABSTRACT:
SUBMITTER: Moon D
PROVIDER: S-EPMC4257241 | biostudies-literature | 2014 Nov
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20141004 Pt 11
In the asymmetric unit of the title compound, [CrF2(C5H5N)4][ZnCl3(C5H5N)]·H2O, there are two independent complex cations, one tri-chlorido-(pyridine-κN)zincate anion and one solvent water mol-ecule. The cations lie on inversion centers. The Cr(III) ions are coordinated by four pyridine (py) N atoms in the equatorial plane and two F atoms in a trans axial arrangement, displaying a slightly distorted octa-hedral geometry. The Cr-N(py) bond lengths are in the range 2.0873 (14) to 2.0926 (17) Å whi ...[more]