Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Di-n-but-yl[4-hy-droxy-N'-(3-meth-oxy-2-oxido-benzyl-idene-?O (2))benzo-hydrazidato-?(2) N,O]tin(IV).

ABSTRACT: In the title compound, [Sn(C4H9)2(C15H12N2O4)], the Sn(IV) atom is coordinated by the N, O and O' atoms from the tridentate Schiff base dianion in an overall cis-C2SnNO2 trigonal-bipyramidal geometry. Adjacent mol-ecules are linked by O-H?O hydrogen bonds, forming a chain running along [001].

SUBMITTER: Qiao Y

PROVIDER: S-EPMC3885005 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Di-n-but-yl[4-hy-droxy-N'-(3-meth-oxy-2-oxido-benzyl-idene-κO (2))benzo-hydrazidato-κ(2) N,O]tin(IV).

Qiao Yanling Y Wang Fei F

Acta crystallographica. Section E, Structure reports online 20131123 Pt 12

In the title compound, [Sn(C4H9)2(C15H12N2O4)], the Sn(IV) atom is coordinated by the N, O and O' atoms from the tridentate Schiff base dianion in an overall cis-C2SnNO2 trigonal-bipyramidal geometry. Adjacent mol-ecules are linked by O-H⋯O hydrogen bonds, forming a chain running along [001]. ...[more]

PMID: 24454180

Similar Datasets

(E)-4-Hy-droxy-N'-(3-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide.

Project description:The mol-ecule of the title benzohydrazide derivative, C(15)H(14)N(2)O(4), exists in a trans conformation with respect to the C=N double bond and is twisted, the dihedral angle between the two benzene rings being 24.17?(6)°. The meth-oxy group is almost co-planar with respect to the attached benzene ring [C(m)-O-C-C (m = meth-yl) = -1.45?(17)°]. In the crystal, the mol-ecules are linked by N-H?O and O-H?O hydrogen bonds into sheets parallel to the bc plane. These sheets are further connected into a three-dimensional network by weak C-H?O and C-H?? inter-actions.

| S-EPMC3201407 | biostudies-literature

(E)-4-Hy-droxy-N'-(4-hy-droxy-3-meth-oxy-benzyl-idene)benzohydrazide.

Project description:In the title compound, C(15)H(14)N(2)O(4), the N=C double bond has an E configuration. The two benzene rings make a dihedral angle of 28.59?(6)°. In the crystal, mol-ecules are linked into a three-dimensional network by inter-molecular N-H?O, O-H?O and C-H?O hydrogen bonds and stabilized by weak C-H?? inter-actions.

| S-EPMC3011781 | biostudies-literature

(E)-4-Hy-droxy-N'-(2-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide.

Project description:In the title compound, C(15)H(14)N(2)O(4), the dihedral angle between the benzene rings is 40.59 (4)° and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring. In the crystal, N-H⋯O, O-H⋯O and C-H⋯O inter-actions link the mol-ecules into a three-dimensional network.

| S-EPMC3394058 | biostudies-literature

N'-(4-Hy-droxy-benzyl-idene)-3-meth-oxy-benzohydrazide.

Project description:In the title compound, C(15)H(14)N(2)O(3), the dihedral angle between the two benzene rings is 47.9 (3)°. In the crystal, mol-ecules are linked through N-H⋯O, O-H⋯O and O-H⋯N hydrogen bonds, forming layers parallel to the ab plane.

| S-EPMC3274989 | biostudies-literature

(E)-N'-(3-Hy-droxy-4-meth-oxy-benzyl-idene)-4-meth-oxy-benzohydrazide.

Project description:The title mol-ecule, a benzohydrazide derivative, C(16)H(16)N(2)O(4), is twisted with a dihedral angle of 69.97 (5)° between the two benzene rings. An intra-molecular O-H⋯O hydrogen bond generates an S(5) ring motif. In the crystal, mol-ecules are linked by N-H⋯O and weak C-H⋯O hydrogen bonds into a chain along the c axis. C-H⋯π inter-actions are also present.

| S-EPMC3239014 | biostudies-literature

(E)-4-Hy-droxy-N'-(2-meth-oxy-benzyl-idene)benzohydrazide.

Project description:In the title compound, C(15)H(14)N(2)O(3), the dihedral angle between the benzene rings is 66.56?(5)°. In the crystal, N-H?O, O-H?O and C-H?O inter-actions link the mol-ecules into a three-dimensional network. A ?-? inter-action, with a centroid-centroid distance of 3.628?(6)?Å, helps to establish the packing.

| S-EPMC3379405 | biostudies-literature

(E)-2-(4-Hy-droxy-3-meth-oxy-benzyl-idene)hydrazinecarboxamide.

Project description:The asymmetric unit of the title compound, C(9)H(11)N(3)O(3), consists of two crystallographically independent mol-ecules. Both mol-ecules are almost planar, with r.m.s. deviations of 0.107 and 0.099 Å. In the crystal, the two independent mol-ecules form a dimer with an R(2) (2)(8) ring motif via N-H⋯O hydrogen bonds. The dimers are further linked into a three-dimensional network by O-H⋯O and N-H⋯O hydrogen bonds.

| S-EPMC3151979 | biostudies-literature

(2E)-2-(4-Hy-droxy-3-meth-oxy-benzyl-idene)hydrazinecarboxamide.

Project description:In the title compound, C(9)H(11)N(3)O(3), two mol-ecules are present in the asymmetric unit in which the 4-hy-droxy-3-meth-oxy-benzaldehyde and hydrazinecarboxamide units are almost planar [with r.m.s. deviations 0.0212 and 0.0066 Å, respectively, in one mol-ecule and 0.0346 and 0.0095 Å, respectively, in the other] and are oriented at dihedral angles of 9.7 (3) and 16.6 (3)°. In both mol-ecules, two S(5) ring motifs are present due to N-H⋯N and O-H⋯O hydrogen bonds. In the crystal, the mol-ecules are dimerized with each other due to pairs of N-H⋯O hydrogen bonds, forming an R(2) (2)(8) ring motif. O-H⋯O hydrogen bonds lead to the formation of a three-dimensional network.

| S-EPMC3393335 | biostudies-literature

2-{[2-(2-Hy-droxy-3-meth-oxy-benzyl-idene)hydrazin-1-yl-idene]meth-yl}-6-meth-oxy-phenol.

Project description:The title compound, C(16)H(16)N(2)O(4), was obtained from the reaction of hydrazine hydrate and o-vanilin in absolute ethanol. The mol-ecule is almost planar (except for the methyl H atoms), with a mean deviation from the plane of 0.0259?Å. The mol-ecular structure also exhibits an approximate non-crystallographic twofold axis. Intra-molecular O-H?N hydrogen bonds occur. In the crystal, inter-molecular C-H?O hydrogen bonds generate mol-ecular zigzag sheets. The sheets stack through C-H?? inter-actions, leading to a three-dimensional-network.

| S-EPMC3201493 | biostudies-literature

2-{[2-(2-Hy-droxy-5-meth-oxy-benzyl-idene)hydrazin-1-yl-idene]meth-yl}-4-meth-oxy-phenol.

Project description:The title phenyl-hydrazine derivative, C16H16N2O4, has a crystallographically imposed centre of symmetry. Except for the methyl group, all non-H atoms are almost coplanar (r.m.s. deviation = 0.0095 Å). Intra-molecular O-H⋯N hydrogen bonds are observed, generating S(6) graph-set ring motifs.

| S-EPMC3998297 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data