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Di-aqua-bis-(2-ethyl-5-methyl-imidazole-4-sulfonato-?(2) N (3),O)nickel(II) dihydrate.

ABSTRACT: In the title complex, [Ni(C6H9N2O3S)2(H2O)2]·2H2O, the Ni(II) atom lies on an inversion center and is chelated by N and O atoms of two symmetry-equivalent imidazole-sulfonate ligands in the basal plane, and two water O atoms in axial positions in an overall octa-hedral configuration. The crystal structure displays O-H?O and N-H?O hydrogen bonds, which connect the components into an extended three-dimensional network.

SUBMITTER: Purdy AP

PROVIDER: S-EPMC3914054 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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Di-aqua-bis-(2-ethyl-5-methyl-imidazole-4-sulfonato-κ(2) N (3),O)nickel(II) dihydrate.

Purdy Andrew P AP Butcher Ray J RJ

Acta crystallographica. Section E, Structure reports online 20131214 Pt 1

In the title complex, [Ni(C6H9N2O3S)2(H2O)2]·2H2O, the Ni(II) atom lies on an inversion center and is chelated by N and O atoms of two symmetry-equivalent imidazole-sulfonate ligands in the basal plane, and two water O atoms in axial positions in an overall octa-hedral configuration. The crystal structure displays O-H⋯O and N-H⋯O hydrogen bonds, which connect the components into an extended three-dimensional network. ...[more]

PMID: 24526946

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