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Crystal structure of 2,2-di-phenyl-hydrazinium chloride.

ABSTRACT: In the title compound, C12H13N2 (+)·Cl(-), the chloride salt of 1,1'-di-phenyl-hydrazine, the phenyl rings are inclined to one another by 78.63?(17)°. The N-(+)NH3 bond lengths is 1.445?(3)?Å, and the N-Cphen-yl bond lengths are 1.435?(3) and 1.447?(4)?Å. In the crystal, mol-ecules are linked via N-H?Cl hydrogen bonds, forming chains along [10-1], which enclose two adjacent R (4) 2(6) ring motifs. The chains are reinforced by C-H?Cl hydrogen bonds.

SUBMITTER: Paul AK

PROVIDER: S-EPMC4257322 | biostudies-literature | 2014 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of 2,2-di-phenyl-hydrazinium chloride.

Paul Amit Kumal AK Mukherjee Soma S Stoeckli-Evans Helen H

Acta crystallographica. Section E, Structure reports online 20141024 Pt 11

In the title compound, C12H13N2 (+)·Cl(-), the chloride salt of 1,1'-di-phenyl-hydrazine, the phenyl rings are inclined to one another by 78.63 (17)°. The N-(+)NH3 bond lengths is 1.445 (3) Å, and the N-Cphen-yl bond lengths are 1.435 (3) and 1.447 (4) Å. In the crystal, mol-ecules are linked via N-H⋯Cl hydrogen bonds, forming chains along [10-1], which enclose two adjacent R (4) 2(6) ring motifs. The chains are reinforced by C-H⋯Cl hydrogen bonds. ...[more]

PMID: 25484752

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