Ontology highlight
ABSTRACT:
SUBMITTER: Suseno S
PROVIDER: S-EPMC3920585 | biostudies-literature | 2013 Dec
REPOSITORIES: biostudies-literature
Suseno Sandy S Horak Kyle T KT Day Michael W MW Agapie Theodor T
Organometallics 20131201 23
Triphosphine and diphosphine ligands with backbones designed to facilitate metal-arene interactions were employed to support multinuclear Ni complexes. Di- and trinuclear metal complexes supported by a triphosphine containing a triarylbenzene linker display diverse metal-arene binding modes. Multinuclear Ni halide complexes were isolated with strongly interacting metal centers bound to opposite faces of the coordinated arene. Upon reaction of the trinickel diiodide complex, <b>2</b>, with disodi ...[more]