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Bis[tris-(1,10-phenanthroline)nickel(II)] tris-[dicyanidoargentate(I)] nitrate 4.2-hydrate.

ABSTRACT: The title compound, [Ni(C(12)H(8)N(2))(3)](2)[Ag(CN)(2)](3)(NO(3))·4.2H(2)O, crystallizes with two independent [Ni(phen)(3)](2+) cations (phen is 1,10-phenanthroline; both Ni atoms have threefold symmetry and N(6) donor sets), three near-linear [Ag(CN)(2)](-) anions, one nitrate anion (N site symmetry 3) and 4.2 water mol-ecules of crystallization, some of which are disordered. The [Ag(CN)(2)](-) anions are situated within cavities created by the phenanthroline ligands of adjacent [Ni(phen)(3)](2+) cations. Some short C-H?O and C-H?N inter-actions may help to establish the packing.

SUBMITTER: Monim-Ul-Mehboob M

PROVIDER: S-EPMC2959559 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Bis[tris-(1,10-phenanthroline)nickel(II)] tris-[dicyanidoargentate(I)] nitrate 4.2-hydrate.

Monim-Ul-Mehboob Muhammad M Tufail Muhammad M Altaf Muhammad M Stoeckli-Evans Helen H Ahmad Saeed S Iftikhar Syed Hassan SH

Acta crystallographica. Section E, Structure reports online 20081009 Pt 11

The title compound, [Ni(C(12)H(8)N(2))(3)](2)[Ag(CN)(2)](3)(NO(3))·4.2H(2)O, crystallizes with two independent [Ni(phen)(3)](2+) cations (phen is 1,10-phenanthroline; both Ni atoms have threefold symmetry and N(6) donor sets), three near-linear [Ag(CN)(2)](-) anions, one nitrate anion (N site symmetry 3) and 4.2 water mol-ecules of crystallization, some of which are disordered. The [Ag(CN)(2)](-) anions are situated within cavities created by the phenanthroline ligands of adjacent [Ni(phen)(3)]( ...[more]

PMID: 21580834

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