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On-resin peptide macrocyclization using thiol-ene click chemistry.

ABSTRACT: A versatile and rapid synthetic strategy has been developed for the on-resin cyclization of peptides using thiol-ene photochemistry. This unique method exploits the thiol group of natural cysteine amino acids and allows for various alkenes to be incorporated orthogonal to the peptide backbone.

SUBMITTER: Aimetti AA 

PROVIDER: S-EPMC3969419 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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On-resin peptide macrocyclization using thiol-ene click chemistry.

Aimetti Alex A AA   Shoemaker Richard K RK   Lin Chien-Chi CC   Anseth Kristi S KS  

Chemical communications (Cambridge, England) 20100408 23

A versatile and rapid synthetic strategy has been developed for the on-resin cyclization of peptides using thiol-ene photochemistry. This unique method exploits the thiol group of natural cysteine amino acids and allows for various alkenes to be incorporated orthogonal to the peptide backbone. ...[more]

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