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Diastereoselective Pt catalyzed cycloisomerization of polyenes to polycycles.

ABSTRACT: Application of a tridentate NHC containing pincer ligand to Pt catalyzed cascade cyclization reactions has allowed for the catalytic, diastereoselective cycloisomerization of biogenic alkene terminated substrates to the their polycyclic counterparts.

SUBMITTER: Geier MJ

PROVIDER: S-EPMC3985707 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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Diastereoselective Pt catalyzed cycloisomerization of polyenes to polycycles.

Geier Michael J MJ Gagné Michel R MR

Journal of the American Chemical Society 20140213 8

Application of a tridentate NHC containing pincer ligand to Pt catalyzed cascade cyclization reactions has allowed for the catalytic, diastereoselective cycloisomerization of biogenic alkene terminated substrates to the their polycyclic counterparts. ...[more]

PMID: 24517454

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