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Rh(I)-Catalyzed Cycloisomerization of 1,6-Enynes.

ABSTRACT: A new and unexpected Rh(I)-catalyzed cycloisomerization of 1,6-enynes is reported. Several different alkyne substitution patterns were evaluated under the reaction conditions, including a deuterated derivative that provides some insight into the reaction mechanism.

SUBMITTER: Matsushima Y 

PROVIDER: S-EPMC4655000 | biostudies-literature | 2015 Jul

REPOSITORIES: biostudies-literature

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Rh(I)-Catalyzed Cycloisomerization of 1,6-Enynes.

Matsushima Yuji Y   Phillips Eric M EM   Bergman Robert G RG   Ellman Jonathan A JA  

Synlett : accounts and rapid communications in synthetic organic chemistry 20150227 11

A new and unexpected Rh(I)-catalyzed cycloisomerization of 1,6-enynes is reported. Several different alkyne substitution patterns were evaluated under the reaction conditions, including a deuterated derivative that provides some insight into the reaction mechanism. ...[more]

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