Applications of C-H functionalization logic to cyclobutane synthesis.
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ABSTRACT: The application of C-H functionalization logic to target-oriented synthesis provides an exciting new venue for the development of new and useful strategies in organic chemistry. In this article, C-H functionalization reactions are explored as an alternative approach to access pseudodimeric cyclobutane natural products, such as the dictazole and the piperarborenine families. The use of these strategies in a variety of complex settings highlights the subtle geometric, steric, and electronic effects at play in the auxiliary guided C-H functionalization of cyclobutanes.
SUBMITTER: Gutekunst WR
PROVIDER: S-EPMC3985916 | biostudies-literature |
REPOSITORIES: biostudies-literature
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