Ontology highlight
ABSTRACT:
SUBMITTER: Zhang K
PROVIDER: S-EPMC3998261 | biostudies-literature | 2014 Feb
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20140122 Pt 2
In the title complex, [Fe(II)Fe(III) 2(C9H10BN6)2(CN)6(CH3OH)4]·2CH3OH, two [Fe(III)(Tp)(CN)3](-) anions [Tp is hydro-tris-(pyrazoylborate)] are bridged by an [Fe(II)(MeOH)4](2+) cation, forming a centrosymmetric trinuclear unit. These units are connected via O-H⋯O and O-H⋯N hydrogen bonds involving the uncoordinated methanol solvent mol-ecules, forming a three-dimensional network. ...[more]