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2-Ferrocenyl-6-(3-nitro-phen-yl)quinoline.

ABSTRACT: In the title compound, [Fe(C5H5)(C20H13N2O2)], the substituted cyclo-penta-dienyl ring and quinoline system are approximately coplanar, making a dihedral angle of 5.18?(6)°, while the dihedral angle between the quinoline system and the benzene ring is 28.45?(8)°. There is high thermal motion in the free cyclo-penta-dienyl ring compared with the substituted cyclo-penta-dienyl ring. The conformation of the two cyclopentadienyl rings in the ferrocenyl moiety is eclipsed.

SUBMITTER: Yuan XE

PROVIDER: S-EPMC3998599 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature

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2-Ferrocenyl-6-(3-nitro-phen-yl)quinoline.

Yuan Xiao-Er XE Shi Guo-Qing GQ Geng Xin X Hao Xin-Qi XQ Song Mao-Ping MP

Acta crystallographica. Section E, Structure reports online 20140308 Pt 4

In the title compound, [Fe(C5H5)(C20H13N2O2)], the substituted cyclo-penta-dienyl ring and quinoline system are approximately coplanar, making a dihedral angle of 5.18 (6)°, while the dihedral angle between the quinoline system and the benzene ring is 28.45 (8)°. There is high thermal motion in the free cyclo-penta-dienyl ring compared with the substituted cyclo-penta-dienyl ring. The conformation of the two cyclopentadienyl rings in the ferrocenyl moiety is eclipsed. ...[more]

PMID: 24826093

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