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N-(2-Chloro-eth-yl)morpholine-4-carbox-amide.

ABSTRACT: The title compound, C7H13ClN2O2, synthesized by the reaction of 2-chloro-ethyl iso-cyanate and morpholine, crystallizes with four molecules in the asymmetric unit, which have similar conformations and comprise two pairs each related by approximate non-crystallographic inversion centres. Two of them have a modest orientational disorder of the 2-chloro-ethyl fragments [occupancy ratio of 0.778?(4):0.222?(4)]. In the crystal, mol-ecules are linked by N-H?O=C hydrogen bonds, forming three crystallographically different kinds of infinite hydrogen-bonded chains extending along [001].

SUBMITTER: Ujam OT

PROVIDER: S-EPMC3998621 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature

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N-(2-Chloro-eth-yl)morpholine-4-carbox-amide.

Ujam Oguejiofo T OT Asegbeloyin Jonnie N JN Nicholson Brian K BK Ukoha Pius O PO Ukwueze Nkechi N NN

Acta crystallographica. Section E, Structure reports online 20140322 Pt 4

The title compound, C7H13ClN2O2, synthesized by the reaction of 2-chloro-ethyl iso-cyanate and morpholine, crystallizes with four molecules in the asymmetric unit, which have similar conformations and comprise two pairs each related by approximate non-crystallographic inversion centres. Two of them have a modest orientational disorder of the 2-chloro-ethyl fragments [occupancy ratio of 0.778 (4):0.222 (4)]. In the crystal, mol-ecules are linked by N-H⋯O=C hydrogen bonds, forming three crystallog ...[more]

PMID: 24826162

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