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TBu3P-Coordinated 2-Phenylaniline-Based Palladacycle Complex As Precatalyst for Pd-Catalyzed Coupling Reactions of Aryl Halides with Polyfluoroarenes via C-H Activation Strategy.


ABSTRACT: tBu3P-Coordinated 2-phenylaniline-based palladacycle complex was demonstrated to be an efficient precatalyst for Pd-catalyzed coupling reactions of aryl halides with polyfluoroarenes via C-H activation strategy. The readily accessibility and easy handling nature of tBu3P- coordinated 2-aminobiphenyl-based palladacycle complex and the high yields of the reaction makes tBu3P-coordinated 2-aminobiphenyl-based palladacycle complex an attractive precatalyst for the cross-coupling reaction of aryl halides with polyfluoroarenes.

SUBMITTER: Zhang HH 

PROVIDER: S-EPMC4000033 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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<i>t</i>Bu<sub>3</sub>P-Coordinated 2-Phenylaniline-Based Palladacycle Complex As Precatalyst for Pd-Catalyzed Coupling Reactions of Aryl Halides with Polyfluoroarenes via C-H Activation Strategy.

Zhang Hong-Hai HH   Dong Jie J   Hu Qiao-Sheng QS  

European journal of organic chemistry 20140201 6


<i>t</i>Bu<sub>3</sub>P-Coordinated 2-phenylaniline-based palladacycle complex was demonstrated to be an efficient precatalyst for Pd-catalyzed coupling reactions of aryl halides with polyfluoroarenes via C-H activation strategy. The readily accessibility and easy handling nature of <i>t</i>Bu<sub>3</sub>P- coordinated 2-aminobiphenyl-based palladacycle complex and the high yields of the reaction makes <i>t</i>Bu<sub>3</sub>P-coordinated 2-aminobiphenyl-based palladacycle complex an attractive p  ...[more]

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