Unknown

Dataset Information

0

Cobalt-Catalyzed Suzuki Biaryl Coupling of Aryl Halides.

ABSTRACT: Readily accessed cobalt pre-catalysts with N-heterocyclic carbene ligands catalyze the Suzuki cross-coupling of aryl chlorides and bromides with alkyllithium-activated arylboronic pinacolate esters. Preliminary mechanistic studies indicate that the cobalt species is reduced to Co0 during the reaction.

SUBMITTER: Asghar S 

PROVIDER: S-EPMC5767760 | biostudies-literature | 2017 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Cobalt-Catalyzed Suzuki Biaryl Coupling of Aryl Halides.

Asghar Soneela S   Tailor Sanita B SB   Elorriaga David D   Bedford Robin B RB  

Angewandte Chemie (International ed. in English) 20171128 51

Readily accessed cobalt pre-catalysts with N-heterocyclic carbene ligands catalyze the Suzuki cross-coupling of aryl chlorides and bromides with alkyllithium-activated arylboronic pinacolate esters. Preliminary mechanistic studies indicate that the cobalt species is reduced to Co<sup>0</sup> during the reaction. ...[more]

Similar Datasets

Unknown Cobalt-Catalyzed Cross-Coupling of Functionalized Alkylzinc Reagents with (Hetero)Aryl Halides.
| S-EPMC7154687 | biostudies-literature
Unknown Ligand-controlled palladium-catalyzed regiodivergent Suzuki-Miyaura cross-coupling of allylboronates and aryl halides.
| S-EPMC3776608 | biostudies-literature
Unknown Biaryl Formation via Base-Promoted Direct Coupling Reactions of Arenes with Aryl Halides.
| S-EPMC8223439 | biostudies-literature
Unknown Palladium-catalyzed borylation of aryl (pseudo)halides and its applications in biaryl synthesis.
| S-EPMC6768141 | biostudies-literature
Unknown Cobalt-catalyzed aminocarbonylation of (hetero)aryl halides promoted by visible light.
| S-EPMC8159399 | biostudies-literature
Unknown Insight into Transmetalation Enables Cobalt-Catalyzed Suzuki-Miyaura Cross Coupling.
| S-EPMC5200927 | biostudies-literature
Unknown A modified procedure for the palladium catalyzed borylation/Suzuki-Miyaura cross-coupling of aryl and heteroaryl halides utilizing bis-boronic acid.
| S-EPMC4525720 | biostudies-literature
Unknown Mechanism and selectivity in nickel-catalyzed cross-electrophile coupling of aryl halides with alkyl halides.
| S-EPMC3946589 | biostudies-literature
Unknown Suzuki-Miyaura cross-coupling of potassium trifluoro(N-methylheteroaryl)borates with aryl and heteroaryl halides.
| S-EPMC3752378 | biostudies-literature
Unknown Nickel-catalyzed decarboxylative cross-coupling of perfluorobenzoates with aryl halides and sulfonates.
| S-EPMC4565129 | biostudies-literature