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(4-Fluoro-phen-yl-?C)(N,N,N',N'-tetra-methyl-ethylenedi-amine-?(2) N,N')(tri-fluoro-meth-yl-?C)palladium(II).

ABSTRACT: In the title compound, [Pd(CF3)(C6H4F)(C6H16N2)], the Pd(II) cation is four-coordinated by the two N atoms of the N,N,N',N'-tetra-methyl-ethylenedi-amine ligand and by one C atom each from a 4-fluoro-phenyl and a tri-fluoro-methyl ligand, in a distorted rectangular-planar geometry, with an average deviation from the least-squares plane of 0.066?(2)?Å. The central coordination angles with the Pd(II) atom range from 83.14?(10) to 97.25?(12)°.

SUBMITTER: Du Y

PROVIDER: S-EPMC4011221 | biostudies-literature | 2014 May

REPOSITORIES: biostudies-literature

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(4-Fluoro-phen-yl-κC)(N,N,N',N'-tetra-methyl-ethylenedi-amine-κ(2) N,N')(tri-fluoro-meth-yl-κC)palladium(II).

Du Youzhi Y Zheng ChangGe C

Acta crystallographica. Section E, Structure reports online 20140416 Pt 5

In the title compound, [Pd(CF3)(C6H4F)(C6H16N2)], the Pd(II) cation is four-coordinated by the two N atoms of the N,N,N',N'-tetra-methyl-ethylenedi-amine ligand and by one C atom each from a 4-fluoro-phenyl and a tri-fluoro-methyl ligand, in a distorted rectangular-planar geometry, with an average deviation from the least-squares plane of 0.066 (2) Å. The central coordination angles with the Pd(II) atom range from 83.14 (10) to 97.25 (12)°. ...[more]

PMID: 24860311

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