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Crystal structure of (4-fluoro-phenyl-?C (1))iodido-(N,N,N',N'-tetra-methyl-ethylenedi-amine-?(2) N,N')palladium(II).

ABSTRACT: In the title compound, [Pd(C6H4F)I(C6H16N2)], the Pd(II) atom is coordinated by two N atoms from the N,N,N',N'-tetra-methyl-ethylenedi-amine ligand, a C atom of the 4-fluoro-phenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-squares plane through the ligand donor atoms of 0.0159?(2)?Å. The angles about the Pd(II) atom range from 83.35?(16) to 178.59?(11)°. In the crystal, weak C-H?F and C-H?I hydrogen bonds link the mol-ecules into sheets in the bc plane.

SUBMITTER: Yan JJ

PROVIDER: S-EPMC4420056 | biostudies-literature | 2015 May

REPOSITORIES: biostudies-literature

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Crystal structure of (4-fluoro-phenyl-κC (1))iodido-(N,N,N',N'-tetra-methyl-ethylenedi-amine-κ(2) N,N')palladium(II).

Yan Jin-Jin JJ Zheng Chang-Ge CG

Acta crystallographica. Section E, Crystallographic communications 20150430 Pt 5

In the title compound, [Pd(C6H4F)I(C6H16N2)], the Pd(II) atom is coordinated by two N atoms from the N,N,N',N'-tetra-methyl-ethylenedi-amine ligand, a C atom of the 4-fluoro-phenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-squares plane through the ligand donor atoms of 0.0159 (2) Å. The angles about the Pd(II) atom range from 83.35 (16) to 178.59 (11)°. In the crystal, weak C-H⋯F and C-H⋯I hydrogen bonds link the mol-ecules into s ...[more]

PMID: 25995896

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