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Octyl (2E)-2-[2-(di-phenyl-phosphan-yl)benzyl-idene]hydrazinecarbodi-thio-ate.

ABSTRACT: The title compound, C28H33N2S2P, adopts the thione tautomeric form, as supported by the C-S distance [1.6744?(18)?Å]. The Schiff base exhibits an E conformation about the C=N bond but a Z conformation about the C-N bond. The terminal chain is disordered over two sets of sites with an occupancy ratio of 0.732?(3):0.268?(3). In the crystal, pairs of N-N-H hydrogen bonds between the thione groups link neighbouring mol-ecules into centrosymmetric dimers.

SUBMITTER: Asri I

PROVIDER: S-EPMC4051045 | biostudies-literature | 2014 Jun

REPOSITORIES: biostudies-literature

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Octyl (2E)-2-[2-(di-phenyl-phosphan-yl)benzyl-idene]hydrazinecarbodi-thio-ate.

Asri Izuddin I Hamid Malai Haniti S A MH Mirza Aminul Huq AH Ali Mohammad Akbar MA Karim Mohammad Rezaul MR

Acta crystallographica. Section E, Structure reports online 20140503 Pt 6

The title compound, C28H33N2S2P, adopts the thione tautomeric form, as supported by the C-S distance [1.6744 (18) Å]. The Schiff base exhibits an E conformation about the C=N bond but a Z conformation about the C-N bond. The terminal chain is disordered over two sets of sites with an occupancy ratio of 0.732 (3):0.268 (3). In the crystal, pairs of N-N-H hydrogen bonds between the thione groups link neighbouring mol-ecules into centrosymmetric dimers. ...[more]

PMID: 24940222

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