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(2E)-2-Benzyl-idene-N-phenyl-hydrazinecarboxamide.

ABSTRACT: The mol-ecule of the title compound, C14H13N3O, adopts an E conformation with respect to the azomethine C=N bond, and is roughly planar, with an r.m.s. deviation of the non-H atoms from the least-squares plane of 0.100?(2)?Å and a dihedral angle between the terminal benzene rings of 5.74?(12)°. An intramolecular N-H?N hydrogen bond closes an S(6) ring. In the crystal, mol-ecules are linked by the pairs of N-H?O hydrogen bonds into centrosymmetric dimers. Dimers related by translation along [010] form slanted stacks, the shortest C?C inter-molecular distance within the stack being 3.283?(3)?Å. Weak C-H?? inter-actions link the stacks into a three-dimensional structure.

SUBMITTER: Layana SR 

PROVIDER: S-EPMC4011198 | biostudies-literature | 2014 May

REPOSITORIES: biostudies-literature

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(2E)-2-Benzyl-idene-N-phenyl-hydrazinecarboxamide.

Layana S R SR   Sithambaresan M M   Siji V L VL   Sudarsanakumar M R MR   Suma S S  

Acta crystallographica. Section E, Structure reports online 20140426 Pt 5

The mol-ecule of the title compound, C14H13N3O, adopts an E conformation with respect to the azomethine C=N bond, and is roughly planar, with an r.m.s. deviation of the non-H atoms from the least-squares plane of 0.100 (2) Å and a dihedral angle between the terminal benzene rings of 5.74 (12)°. An intramolecular N-H⋯N hydrogen bond closes an S(6) ring. In the crystal, mol-ecules are linked by the pairs of N-H⋯O hydrogen bonds into centrosymmetric dimers. Dimers related by translation along [010]  ...[more]

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