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Stereochemical control of the Passerini reaction.

ABSTRACT: A catalytic asymmetric Passerini reaction using tridentate indan (pybox) Cu(II) Lewis acid complex 4 with substrates capable of bidentate coordination has been achieved. The reaction occurs via ligand-accelerated catalysis.

SUBMITTER: Andreana PR

PROVIDER: S-EPMC4134661 | biostudies-literature | 2004 Nov

REPOSITORIES: biostudies-literature

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Stereochemical control of the Passerini reaction.

Andreana Peter R PR Liu Chang C CC Schreiber Stuart L SL

Organic letters 20041101 23

A catalytic asymmetric Passerini reaction using tridentate indan (pybox) Cu(II) Lewis acid complex 4 with substrates capable of bidentate coordination has been achieved. The reaction occurs via ligand-accelerated catalysis. ...[more]

PMID: 15524450

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