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An Enantioselective Synthesis of a MEM-Protected Aetheramide A Derivative.


ABSTRACT: Aetheramides A and B are very potent anti-HIV agents. An enantioselective synthesis of a MEM-protected aetheramide A derivative is described. The synthesis was accomplished in a convergent and stereoselective manner. The key reactions involved asymmetric dihydroxylation, asymmetric allylation, asymmetric syn-aldol reactions and asymmetric hydrogenation.

SUBMITTER: Ghosh AK 

PROVIDER: S-EPMC4153992 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature

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An Enantioselective Synthesis of a MEM-Protected Aetheramide A Derivative.

Ghosh Arun K AK   Rao Kalapala Venkateswara KV   Akasapu Siddhartha S  

Tetrahedron letters 20140901 37


Aetheramides A and B are very potent anti-HIV agents. An enantioselective synthesis of a MEM-protected aetheramide A derivative is described. The synthesis was accomplished in a convergent and stereoselective manner. The key reactions involved asymmetric dihydroxylation, asymmetric allylation, asymmetric <i>syn</i>-aldol reactions and asymmetric hydrogenation. ...[more]

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