Bis{2-meth-oxy-6-[(E)-(4-methyl-benz-yl)imino-meth-yl]phenolato}palladium(II) chloro-form monosolvate.

ABSTRACT: In the title complex, [Pd(C16H16NO2)2]·CHCl3, the Pd(II) cation lies on an inversion center. One Cl atom of the CHCl3 solvent mol-ecule lies on a twofold axis and the C-H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The Pd(II) cation is four-coordinate and adopts a square-planar geometry via coordination of the imine N and phenolic O atoms of the two bidentate Schiff base anions. The N and O atoms of these ligands are mutually trans. The plane of the benzene ring makes a dihedral angle of 73.52?(10)° with that of the meth-oxy-phenolate ring. In the crystal, mol-ecules of the Pd(II) complex are arranged into sheets parallel to the ac plane, and the chloro-form solvent mol-ecules are located in the inter-stitial areas between the complex mol-ecules. Weak inter-molecular C-H?O and C-H?? inter-actions stabilize the packing.

SUBMITTER: Bahron H 

PROVIDER: S-EPMC4158526 | biostudies-literature | 2014 Aug

REPOSITORIES: biostudies-literature