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Cis-Dichloridobis(2-isocyano-phenyl 4-meth-oxy-benzoate)palladium(II) chloro-form monosolvate.

ABSTRACT: In the title compound, [PdCl2(C15H11NO3)2]·CHCl3, the Pd(II) atom adopts a slightly distorted square-planar coordination geometry composed of two Cl atoms in cis positions and two C atoms from isocyano-phenyl ligands. The mol-ecular conformation is stabilized by ?-? stacking inter-actions [shortest centroid-centroid distance = 3.600?(1)?Å] between substituted benzene rings of different ligands. The crystal packing is characterized by C-H?O and C-H?Cl inter-actions involving the chloro-form solvent mol-ecules.

SUBMITTER: Tskhovrebov A

PROVIDER: S-EPMC3588737 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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cis-Dichloridobis(2-isocyano-phenyl 4-meth-oxy-benzoate)palladium(II) chloro-form monosolvate.

Tskhovrebov Alexander A Haukka Matti M

Acta crystallographica. Section E, Structure reports online 20121114 Pt 12

In the title compound, [PdCl2(C15H11NO3)2]·CHCl3, the Pd(II) atom adopts a slightly distorted square-planar coordination geometry composed of two Cl atoms in cis positions and two C atoms from isocyano-phenyl ligands. The mol-ecular conformation is stabilized by π-π stacking inter-actions [shortest centroid-centroid distance = 3.600 (1) Å] between substituted benzene rings of different ligands. The crystal packing is characterized by C-H⋯O and C-H⋯Cl inter-actions involving the chloro-form solve ...[more]

PMID: 23468702

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