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Crystal structure of 3-({[(thio-phen-2-yl)methyl-idene]hydrazin-yl}carbon-yl)pyridinium chloride dihydrate.

ABSTRACT: In the title compound, C11H10N3OS(+)·Cl(-)·2H2O, the organic cation exhibits a dihedral angle of 21.26?(8)° between the mean planes of the pyridine and thio-phene rings, and dihedral angles of 15.11?(9) and 6.49?(9)° between the mean planes of the hydrazide moiety and the pyridine and thio-phene rings, respectively. In the crystal, the organic cation, the chloride counter-anion and the two water mol-ecules of crystallization are linked through an intricate hydrogen-bonding network consisting of O-H?O, O-H?N, N-H?Cl, C-H?Cl, C-H?O, N-H?O, O-H?Cl and C-H?S inter-actions that consolidate a three-dimensional network.

SUBMITTER: Chandrasekaran T

PROVIDER: S-EPMC4186149 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature

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Crystal structure of 3-({[(thio-phen-2-yl)methyl-idene]hydrazin-yl}carbon-yl)pyridinium chloride dihydrate.

Chandrasekaran Thangayyah T Suresh Mani M Josephine Novina John J Syed Ali Padusha Mohamed Khan MK Vasuki Gopalsamy G Kasthuri Balasubramani B

Acta crystallographica. Section E, Structure reports online 20140806 Pt 9

In the title compound, C11H10N3OS(+)·Cl(-)·2H2O, the organic cation exhibits a dihedral angle of 21.26 (8)° between the mean planes of the pyridine and thio-phene rings, and dihedral angles of 15.11 (9) and 6.49 (9)° between the mean planes of the hydrazide moiety and the pyridine and thio-phene rings, respectively. In the crystal, the organic cation, the chloride counter-anion and the two water mol-ecules of crystallization are linked through an intricate hydrogen-bonding network consisting of ...[more]

PMID: 25309289

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