Unknown

Dataset Information

0

Crystal structure of 2-{[2-(3-phenyl-allyl-idene)hydrazin-1-yl]thio-carbonyl-sulfanylmeth-yl}pyridinium chloride.

ABSTRACT: In the title salt of an S-substituted di-thio-carbazate, C16H16N3S2 (+)·Cl(-), the dihedral angles between the almost planar (r.m.s deviation = 0.005?Å) central CN2S2 residue and the terminal pyridinium and phenyl rings are 80.09?(11) and 3.82?(11)°, respectively, indicating the cation has an L-shape; the amine H and thione S atoms are syn. The conformation about each of the imine [1.376?(3)?Å] and ethene [1.333?(4)?Å] bonds is E. The shortened C-C bond [1.444?(4)?Å] linking the double bonds is consistent with conjugation in this part of the mol-ecule. In the crystal, supra-molecular layers with a jagged topology are formed by charged-assisted amine-H?Cl(-) and pyridinium-N(+)-H?Cl(-) hydrogen bonds. The layers stack along the a axis with no specific directional inter-actions between them.

SUBMITTER: Low ML 

PROVIDER: S-EPMC4257274 | biostudies-literature | 2014 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of 2-{[2-(3-phenyl-allyl-idene)hydrazin-1-yl]thio-carbonyl-sulfanylmeth-yl}pyridinium chloride.

Low May Lee ML   Ravoof Thahira Begum S A TB   Tahir Mohamed Ibrahim Mohamed MI   Crouse Karen A KA   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20141029 Pt 11

In the title salt of an S-substituted di-thio-carbazate, C16H16N3S2 (+)·Cl(-), the dihedral angles between the almost planar (r.m.s deviation = 0.005 Å) central CN2S2 residue and the terminal pyridinium and phenyl rings are 80.09 (11) and 3.82 (11)°, respectively, indicating the cation has an L-shape; the amine H and thione S atoms are syn. The conformation about each of the imine [1.376 (3) Å] and ethene [1.333 (4) Å] bonds is E. The shortened C-C bond [1.444 (4) Å] linking the double bonds is  ...[more]

Similar Datasets

Unknown Crystal structure of 3-({[(thio-phen-2-yl)methyl-idene]hydrazin-yl}carbon-yl)pyridinium chloride dihydrate.
| S-EPMC4186149 | biostudies-literature
Unknown Crystal structure of (E)-3-{[2-(2,4-di-chloro-benzyl-idene)hydrazin-1-yl]carbon-yl}pyridinium chloride trihydrate.
| S-EPMC4384619 | biostudies-literature
Unknown N'-[(1E,2E)-1-(2-Phenyl-hydrazin-1-yl-idene)-1-(phenyl-sulfon-yl)propan-2-yl-idene]benzohydrazide.
| S-EPMC3200681 | biostudies-literature
Unknown Crystal structure of (E)-4-{1-[2-(car-bamo-thio-yl)hydrazin-1-yl-idene]ethyl}phenyl 4-methyl-benzoate.
| S-EPMC4331904 | biostudies-literature
Unknown (E)-1-Phenyl-2-({5-[(1E)-(2-phenyl-hydrazin-1-yl-idene)meth-yl]-2-thien-yl}methyl-idene)hydrazine.
| S-EPMC2983505 | biostudies-literature
Unknown (2E)-2-(2-Phenyl-hydrazin-1-yl-idene)propanoic acid.
| S-EPMC3089133 | biostudies-literature
Unknown 3-(2-Ethyl-2-phenyl-hydrazin-1-yl-idene)indolin-2-one.
| S-EPMC3589046 | biostudies-literature
Unknown Ethyl (Z)-2-chloro-2-(2-phenyl-hydrazin-1-yl-idene)acetate.
| S-EPMC3007979 | biostudies-literature
Unknown 1-(4-Nitro-phen-yl)-2-(3-phenyl-allyl-idene)hydrazine.
| S-EPMC2962156 | biostudies-literature
Unknown (Pyridin-4-yl)methyl N'-(3-phenyl-allyl-idene)hydrazinecarbodithio-ate.
| S-EPMC3569232 | biostudies-literature