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Structural characterization of the μ-Nitrido Complex {[Fe(OEP)]2N}


ABSTRACT: The molecular structure of the μ-nitrido dimer, μ-nitrido-bis(2,3,7,8,12,13, 17,18-octaethylporphyrinato)iron, is reported. The axial Fe-N distances average to 1.657 (11) Å and the equatorial distances average to 2.005(5) Å. Although not required by symmetry, the two iron centers appear equivalent and are consistent with an assignment of a low-spin state and a formal oxidation state of +3.5. A comparison of this structure with other nitrido-bridged species is given.

SUBMITTER: Li M 

PROVIDER: S-EPMC4221236 | biostudies-literature | 2014 May

REPOSITORIES: biostudies-literature

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Structural characterization of the <i>μ</i>-Nitrido Complex {[Fe(OEP)]<sub>2</sub>N}

Li Ming M   Scheidt W Robert WR  

Journal of porphyrins and phthalocyanines 20140501 5


The molecular structure of the <i>μ</i>-nitrido dimer, <i>μ</i>-nitrido-bis(2,3,7,8,12,13, 17,18-octaethylporphyrinato)iron, is reported. The axial Fe-N distances average to 1.657 (11) Å and the equatorial distances average to 2.005(5) Å. Although not required by symmetry, the two iron centers appear equivalent and are consistent with an assignment of a low-spin state and a formal oxidation state of +3.5. A comparison of this structure with other nitrido-bridged species is given. ...[more]

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