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Synthesis and structural characterization of hexa-?2-chlorido-?4-oxido-tetra-kis-{[4-(phenyl-ethyn-yl)pyridine-?N]copper(II)} di-chloro-methane monosolvate.

ABSTRACT: In the crystal structure of the title compound, [Cu4Cl6O(C13H9N)4]·CH2Cl2, the core mol-ecular structure consists of a Cu4 tetra-hedron with a central inter-stitial O atom. Each edge of the Cu4 tetra-hedron is bridged by a chlorido ligand. Each copper(II) cation is coordinated to the central O atom, two chlorido ligands and one N atom of the 4-phenyl-ethynyl-pyridine ligand. In the crystal, the mol-ecules are linked by inter-molecular C-H?Cl inter-actions. Furthermore, C-H?? and ?-? inter-actions also connect the mol-ecules, forming a three-dimensional network. Hirshfeld surface analysis indicates that the most important contributions for the packing arrangement are from H?H and C?H/H?C inter-actions.

SUBMITTER: Al Balushi RA 

PROVIDER: S-EPMC7784052 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature

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Synthesis and structural characterization of hexa-μ<sub>2</sub>-chlorido-μ<sub>4</sub>-oxido-tetra-kis-{[4-(phenyl-ethyn-yl)pyridine-κ<i>N</i>]copper(II)} di-chloro-methane monosolvate.

Al Balushi Rayya A RA   Khan Muhammad S MS   Faizi Md Serajul Haque MSH   Haque Ashanul A   Molloy Kieran K   Raithby Paul R PR  

Acta crystallographica. Section E, Crystallographic communications 20210101 Pt 1

In the crystal structure of the title compound, [Cu<sub>4</sub>Cl<sub>6</sub>O(C<sub>13</sub>H<sub>9</sub>N)<sub>4</sub>]·CH<sub>2</sub>Cl<sub>2</sub>, the core mol-ecular structure consists of a Cu<sub>4</sub> tetra-hedron with a central inter-stitial O atom. Each edge of the Cu<sub>4</sub> tetra-hedron is bridged by a chlorido ligand. Each copper(II) cation is coordinated to the central O atom, two chlorido ligands and one <i>N</i> atom of the 4-phenyl-ethynyl-pyridine ligand. In the crystal,  ...[more]

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