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Crystal structure of nitrido[5,10,15,20-tetra-kis(4-methylphenyl)-porphyrinato]-manganese(V).

ABSTRACT: The title compound, [Mn(C48H36N4)(N)], is a manganese(V) complex with the transition metal in a square-pyramidal coordination geometry and a nitride as the axial ligand. The complex resides on a crystallographic inversion center and only one half of it is symmetry independent. The Mn(V) atom and the nitride N atom are equally disordered across the inversion center. The Mn N distance is 1.516?(4)?Å. The Mn(V) atom is displaced from the plane defined by the four equatorial nitro-gen atoms toward the nitride ligand by 0.3162?(6)?Å.

SUBMITTER: Shields MR

PROVIDER: S-EPMC4257217 | biostudies-literature | 2014 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of nitrido[5,10,15,20-tetra-kis(4-methylphenyl)-porphyrinato]-manganese(V).

Shields Mason R MR Guzei Ilia A IA Goll James G JG

Acta crystallographica. Section E, Structure reports online 20140924 Pt 10

The title compound, [Mn(C48H36N4)(N)], is a manganese(V) complex with the transition metal in a square-pyramidal coordination geometry and a nitride as the axial ligand. The complex resides on a crystallographic inversion center and only one half of it is symmetry independent. The Mn(V) atom and the nitride N atom are equally disordered across the inversion center. The Mn N distance is 1.516 (4) Å. The Mn(V) atom is displaced from the plane defined by the four equatorial nitro-gen atoms toward t ...[more]

PMID: 25484663

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