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Crystal structure of tri-aqua-(1,10-phen-anthroline-?(2) N,N')(2,4,5-tri-fluoro-3-meth-oxy-benzoato-?O (1))cobalt(II) 2,4,5-tri-fluoro-3-meth-oxy-benzoate.

ABSTRACT: The title salt, [Co(C8H4F3O3)(C12H8N2)(H2O)3](C8H4F3O3), was obtained under solvothermal conditions by the reaction of 2,4,5-tri-fluoro-3-meth-oxy-benzoic acid with CoCl2 in the presence of 1,10-phenanthroline (phen). The Co(II) ion is octa-hedrally coordinated by two N atoms [Co-N = 2.165?(2) and 2.129?(2)?Å] from the phen ligand, by one carboxyl-ate O atom [Co-O = 2.107?(1)?Å] and by three O atoms from water mol-ecules [Co-O = 2.093?(1), 2.102?(1) and 2.114?(1)?Å]. The equatorial positions of the slightly distorted octa-hedron are occupied by the N atoms, the carboxyl-ate O and one water O atom. An intra- and inter-molecular O-H?O hydrogen-bonding network between the water-containing complex cation and the organic anion leads to the formation of ribbons parallel to [010].

SUBMITTER: Sun J

PROVIDER: S-EPMC4257257 | biostudies-literature | 2014 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of tri-aqua-(1,10-phen-anthroline-κ(2) N,N')(2,4,5-tri-fluoro-3-meth-oxy-benzoato-κO (1))cobalt(II) 2,4,5-tri-fluoro-3-meth-oxy-benzoate.

Sun Junshan J

Acta crystallographica. Section E, Structure reports online 20141011 Pt 11

The title salt, [Co(C8H4F3O3)(C12H8N2)(H2O)3](C8H4F3O3), was obtained under solvothermal conditions by the reaction of 2,4,5-tri-fluoro-3-meth-oxy-benzoic acid with CoCl2 in the presence of 1,10-phenanthroline (phen). The Co(II) ion is octa-hedrally coordinated by two N atoms [Co-N = 2.165 (2) and 2.129 (2) Å] from the phen ligand, by one carboxyl-ate O atom [Co-O = 2.107 (1) Å] and by three O atoms from water mol-ecules [Co-O = 2.093 (1), 2.102 (1) and 2.114 (1) Å]. The equatorial positions of ...[more]

PMID: 25484778

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