Unknown

Dataset Information

0

Crystal structure of tert-butyl-N-phenyl-carbonitrilium tetra-chlorido-aluminate.


ABSTRACT: In the title compound, (C11H14N)[AlCl4], the nitrilium (systematic name: 2,2-dimethyl-N-phenyl-propane-nitrilium) ion adopts a slightly distorted linear configuration [C-N C = 178.87?(16) and N C-C = 179.13?(17)°]. In the crystal, while there are no inter-molecular hydrogen bonds, pairs of nitrilium ions are linked through ?-? inter-actions [inter-centroid distance = 3.8091?(13)?Å].

SUBMITTER: van Dijk T 

PROVIDER: S-EPMC4257323 | biostudies-literature | 2014 Nov

REPOSITORIES: biostudies-literature

altmetric image

Publications

Crystal structure of tert-butyl-N-phenyl-carbonitrilium tetra-chlorido-aluminate.

van Dijk Tom T   Zant Dirk W DW   Wolf Robert R   Lammertsma Koop K   Slootweg J Chris JC  

Acta crystallographica. Section E, Structure reports online 20141011 Pt 11


In the title compound, (C11H14N)[AlCl4], the nitrilium (systematic name: 2,2-dimethyl-N-phenyl-propane-nitrilium) ion adopts a slightly distorted linear configuration [C-N C = 178.87 (16) and N C-C = 179.13 (17)°]. In the crystal, while there are no inter-molecular hydrogen bonds, pairs of nitrilium ions are linked through π-π inter-actions [inter-centroid distance = 3.8091 (13) Å]. ...[more]

Similar Datasets

| S-EPMC3790365 | biostudies-literature
| S-EPMC4910352 | biostudies-literature
| S-EPMC5382622 | biostudies-literature
| S-EPMC4257444 | biostudies-literature
| S-EPMC3588519 | biostudies-literature
| S-EPMC5946985 | biostudies-literature
| S-EPMC4719953 | biostudies-literature
| S-EPMC3275182 | biostudies-other
| S-EPMC4459331 | biostudies-literature
| S-EPMC3011620 | biostudies-literature