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Crystal structure of tricarbon-yl(N-di-phenyl-phosphanyl-N,N'-diisopropyl-P-phenyl-phospho-nous di-amide-?(2) P,P')cobalt(I) tetra-carbonyl-cobaltate(-I) toluene 0.25-solvate.

ABSTRACT: The asymmetric unit of the title compound, [Co(C24H30N2P2)(CO)3][Co(CO)4]·0.25C7H8, consists of two crystallographically independent cations with similar conformations, two anions, and one-half of a toluene mol-ecule disordered about an inversion centre. In the cations, a Co/P/N/P four-membered slightly bent metallacycle is the key structural element. The pendant NH group is not coordinated to the Co(I) atom, which displays a distorted trigonal-bipyramidal coordination geometry. Weak inter-ionic hydrogen bonds are observed between the NH groups and a carbonyl group of the tetrahedral [Co(CO)4](-) anions.

SUBMITTER: Dura L 

PROVIDER: S-EPMC4257381 | biostudies-literature | 2014 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of tricarbon-yl(N-di-phenyl-phosphanyl-N,N'-diisopropyl-P-phenyl-phospho-nous di-amide-κ(2) P,P')cobalt(I) tetra-carbonyl-cobaltate(-I) toluene 0.25-solvate.

Dura Laura L   Spannenberg Anke A   Beweries Torsten T  

Acta crystallographica. Section E, Structure reports online 20141119 Pt 12

The asymmetric unit of the title compound, [Co(C24H30N2P2)(CO)3][Co(CO)4]·0.25C7H8, consists of two crystallographically independent cations with similar conformations, two anions, and one-half of a toluene mol-ecule disordered about an inversion centre. In the cations, a Co/P/N/P four-membered slightly bent metallacycle is the key structural element. The pendant NH group is not coordinated to the Co(I) atom, which displays a distorted trigonal-bipyramidal coordination geometry. Weak inter-ionic  ...[more]

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