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Crystal structure of tin(II) perchlorate trihydrate.

ABSTRACT: The title compound, [Sn(H2O)3](ClO4)2, was synthesized by the redox reaction of copper(II) perchlorate hexa-hydrate and metallic tin in perchloric acid. Both the trigonal-pyramidal [Sn(H2O)3](2+) cations and tetra-hedral perchlorate anions lie on crystallographic threefold axes. In the crystal, the cations are linked to the anions by O-H?O hydrogen bonds, generating (001) sheets.

SUBMITTER: Hennings E

PROVIDER: S-EPMC4257428 | biostudies-literature | 2014 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of tin(II) perchlorate trihydrate.

Hennings Erik E Schmidt Horst H Köhler Martin M Voigt Wolfgang W

Acta crystallographica. Section E, Structure reports online 20141112 Pt 12

The title compound, [Sn(H2O)3](ClO4)2, was synthesized by the redox reaction of copper(II) perchlorate hexa-hydrate and metallic tin in perchloric acid. Both the trigonal-pyramidal [Sn(H2O)3](2+) cations and tetra-hedral perchlorate anions lie on crystallographic threefold axes. In the crystal, the cations are linked to the anions by O-H⋯O hydrogen bonds, generating (001) sheets. ...[more]

PMID: 25552969

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