Ontology highlight
ABSTRACT:
SUBMITTER: Devari S
PROVIDER: S-EPMC4273296 | biostudies-literature | 2014
REPOSITORIES: biostudies-literature
Devari Shekaraiah S Kumar Manjeet M Deshidi Ramesh R Rizvi Masood M Shah Bhahwal Ali BA
Beilstein journal of organic chemistry 20141112
A novel metal-free strategy for a rapid and α-selctive C-alkynylation of glycals was developed. The reaction utilizes TMSOTf as a promoter to generate in situ trimethylsilylacetylene for C-alkynylation. Thanks to this methodology, we can access C-glycosides in a single step from a variety of acetylenes , i.e., arylacetylenes and most importantly aliphatic alkynes. ...[more]