Unknown

Dataset Information

0

Rationale for the sluggish oxidative addition of aryl halides to Au(I).


ABSTRACT: The oxidative addition of Csp(2)-Br or Csp(2)-I bonds to gold(I) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(III) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish.

SUBMITTER: Livendahl M 

PROVIDER: S-EPMC4295554 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

altmetric image

Publications

Rationale for the sluggish oxidative addition of aryl halides to Au(I).

Livendahl Madeleine M   Goehry Charles C   Maseras Feliu F   Echavarren Antonio M AM  

Chemical communications (Cambridge, England) 20140201 13


The oxidative addition of Csp(2)-Br or Csp(2)-I bonds to gold(I) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(III) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish. ...[more]

Similar Datasets

| S-EPMC5603523 | biostudies-literature
| S-EPMC7189616 | biostudies-literature
| S-EPMC6449856 | biostudies-literature
| S-EPMC6566379 | biostudies-literature
| S-EPMC5725734 | biostudies-literature
| S-EPMC10472430 | biostudies-literature
| S-EPMC9076196 | biostudies-literature
| S-EPMC4046758 | biostudies-literature
| S-EPMC5767760 | biostudies-literature
| S-EPMC3946589 | biostudies-literature