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ABSTRACT:
SUBMITTER: Livendahl M
PROVIDER: S-EPMC4295554 | biostudies-literature | 2014 Feb
REPOSITORIES: biostudies-literature
Livendahl Madeleine M Goehry Charles C Maseras Feliu F Echavarren Antonio M AM
Chemical communications (Cambridge, England) 20140201 13
The oxidative addition of Csp(2)-Br or Csp(2)-I bonds to gold(I) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(III) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish. ...[more]