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Crystal structure of N (1)-phenyl-N (4)-[(E)-(pyren-1-yl)methyl-idene]benzene-1,4-di-amine.

ABSTRACT: In the title compound, C29H20N2, the dihedral angles subtended by the central p-phenyl-enedi-amine ring with respect to the mean plane of the terminal pyrenyl ring system (r.m.s. deviation = 0.027?Å) and the terminal N-phenyl ring are 29.34?(4) and 43.43?(7)°, respectively. The conformation about the C=N bond is E. In the crystal, mol-ecules are linked by N-H?? and C-H?? inter-actions forming chains propagating along the [10-2] direction. These chains are linked via ?-? inter-actions [inter-centroid distances are in the range 3.5569?(11)-3.708?(1)?Å], forming slabs lying parallel to (30-4).

SUBMITTER: Faizi MS

PROVIDER: S-EPMC4350710 | biostudies-literature | 2015 Mar

REPOSITORIES: biostudies-literature

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Crystal structure of N (1)-phenyl-N (4)-[(E)-(pyren-1-yl)methyl-idene]benzene-1,4-di-amine.

Faizi Md Serajul Haque MS Prisyazhnaya Elena V EV

Acta crystallographica. Section E, Crystallographic communications 20150207 Pt 3

In the title compound, C29H20N2, the dihedral angles subtended by the central p-phenyl-enedi-amine ring with respect to the mean plane of the terminal pyrenyl ring system (r.m.s. deviation = 0.027 Å) and the terminal N-phenyl ring are 29.34 (4) and 43.43 (7)°, respectively. The conformation about the C=N bond is E. In the crystal, mol-ecules are linked by N-H⋯π and C-H⋯π inter-actions forming chains propagating along the [10-2] direction. These chains are linked via π-π inter-actions [inter-cent ...[more]

PMID: 25844182

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