Ontology highlight
ABSTRACT:
SUBMITTER: Bruno G
PROVIDER: S-EPMC4384546 | biostudies-literature | 2015 Feb
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20150128 Pt 2
In the centrosymmetric dinuclear title compound, [Pd2(C4H7)2(C16H14N2S2)], the metal atom is η(3)-coordinated by three C atoms of a crotyl ligand [Pd-C = 2.147 (4), 2.079 (5) and 2.098 (5) Å], the longest distance influenced by the steric inter-action with the benzyl substituents of the di-benzyl-dithio-oximidate (DTO) ligand. The Pd-N and Pd-S bonds to this ligand are 2.080 (3) and 2.3148 (9) Å, respectively, completing a square-planar coordination environment for Pd(II). The benzyl groups are ...[more]