Unknown

Dataset Information

0

Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)meth-yl]pyridinium iodide.

ABSTRACT: In the title salt, C10H11N4O2 (+)·I(-), the asymmetric unit consists of a pyridinium cation bearning a (1-methyl-5-nitro-1H-imidazol-2-yl)methyl group at the N position and an iodide anion. The imidazole ring is quasiplanar, with a maxiumum deviation of 0.0032?(16)?Å, and forms a dihedral angle of 67.39?(6)° with the plane of the pyridinium ring. The crystal packing can be described as alternating zigzag layers of cations parallel to the (001) plane, which are sandwiched by the iodide ions. The structure features two types of hydrogen bonds (C-H?O and C-H?I), viz. cation-anion and cation-cation, which lead to the form ation of a three-dimensional network.

SUBMITTER: Belguedj R 

PROVIDER: S-EPMC4384567 | biostudies-literature | 2015 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)meth-yl]pyridinium iodide.

Belguedj Roumaissa R   Bouraiou Abdelmalek A   Merazig Hocine H   Belfaitah Ali A   Bouacida Sofiane S  

Acta crystallographica. Section E, Crystallographic communications 20150128 Pt 2

In the title salt, C10H11N4O2 (+)·I(-), the asymmetric unit consists of a pyridinium cation bearning a (1-methyl-5-nitro-1H-imidazol-2-yl)methyl group at the N position and an iodide anion. The imidazole ring is quasiplanar, with a maxiumum deviation of 0.0032 (16) Å, and forms a dihedral angle of 67.39 (6)° with the plane of the pyridinium ring. The crystal packing can be described as alternating zigzag layers of cations parallel to the (001) plane, which are sandwiched by the iodide ions. The  ...[more]

Similar Datasets

Unknown 5-[(2-Methyl-4-nitro-1H-imidazol-1-yl)meth-yl]-1,3,4-thia-diazol-2-amine.
| S-EPMC3885074 | biostudies-literature
Unknown 1-Methyl-4-(1-methyl-1H-benzimidazol-2-yl)pyridinium iodide.
| S-EPMC2980206 | biostudies-literature
Unknown Crystal structure of 2-{[1-(2-methyl-5-nitro-1H-imidazol-1-yl)propan-2-yl-oxy]carbon-yl}benzoic acid.
| S-EPMC4257427 | biostudies-literature
Unknown Methyl 2-(2-methyl-4-nitro-1H-imidazol-1-yl)acetate.
| S-EPMC3684924 | biostudies-literature
Unknown 1-[(1-Methyl-1H-imidazol-5-yl)meth-yl]-1H-indole-5-carbonitrile.
| S-EPMC3589058 | biostudies-literature
Unknown 1-(2-Methyl-5-nitro-1H-imidazol-1-yl)acetone.
| S-EPMC3629604 | biostudies-literature
Unknown Crystal structure of 4-{2-[4-(di-methyl-amino)-phen-yl]diazen-1-yl}-1-methyl-pyridinium iodide.
| S-EPMC4719983 | biostudies-literature
Unknown (E)-N'-(4-Meth-oxy-benzyl-idene)-2-(2-methyl-4-nitro-1H-imidazol-1-yl)acetohydrazide.
| S-EPMC3470350 | biostudies-literature
Unknown 2-(2-Methyl-5-nitro-1H-imidazol-1-yl)ethyl 2-nitro-benzoate.
| S-EPMC2983685 | biostudies-literature
Unknown Ethyl 2-(2-methyl-4-nitro-1H-imidazol-1-yl)acetate.
| S-EPMC2983319 | biostudies-literature