(E)-N'-(4-Meth-oxy-benzyl-idene)-2-(2-methyl-4-nitro-1H-imidazol-1-yl)acetohydrazide.

ABSTRACT: In the title compound, C(14)H(15)N(5)O(4), the central -C=N-N-C(=O)-C- bridge is nearly planar [maximum deviation = 0.037?(1)?Å] and forms dihedral angles of 7.37?(9) and 73.33?(5)°, respectively, with the benzene and imidazole rings. The dihedral angle between the benzene and imidazole rings is 66.08?(9)°. The meth-oxy and nitro groups are nearly coplanar with the benzene and imidazole rings, respectively, with a C-O-C-C torsion angle of 5.9?(2)° and an O-N-C-C angle of -0.2?(2)°. In the crystal, mol-ecules are linked by a pair of N-H?O hydrogen bonds with an R(2) (2)(8) ring motif, forming an inversion dimer. The dimers are further inter-connected by C-H?O hydrogen bonds into a sheet parallel to the (111) plane. A C-H?? inter-action is also observed between the sheets.

SUBMITTER: Fun HK 

PROVIDER: S-EPMC3470350 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature