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(E)-4-Meth-oxy-N'-[(pyridin-4-yl)methyl-idene]benzohydrazide monohydrate.

ABSTRACT: In the title compound, C(14)H(13)N(3)O(2)·H(2)O, the azomethine double bond adopts an E conformation and the N-N=C-C torsion angle is 178.37?(19)°. The dihedral angle between the benzene and pyridine rings is 5.58?(12)° and the C atom of the meth-oxy group is roughly coplanar with its attached ring [deviation = 0.157?(3)?Å]. In the crystal, the components are linked by O-H?O, O-H?N, N-H?O and C-H?O hydrogen bonds, forming (001) sheets. The water O atom accepts one N-H?O and two C-H?O inter-actions from the adjacent organic mol-ecule.

SUBMITTER: Taha M

PROVIDER: S-EPMC3435810 | biostudies-other | 2012 Sep

REPOSITORIES: biostudies-other

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(E)-4-Meth-oxy-N'-[(pyridin-4-yl)methyl-idene]benzohydrazide monohydrate.

Taha Muhammad M Naz Humera H Rahman Aqilah Abd AA Ismail Nor Hadiani NH Sammer Yousuf Y

Acta crystallographica. Section E, Structure reports online 20120825 Pt 9

In the title compound, C(14)H(13)N(3)O(2)·H(2)O, the azomethine double bond adopts an E conformation and the N-N=C-C torsion angle is 178.37 (19)°. The dihedral angle between the benzene and pyridine rings is 5.58 (12)° and the C atom of the meth-oxy group is roughly coplanar with its attached ring [deviation = 0.157 (3) Å]. In the crystal, the components are linked by O-H⋯O, O-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds, forming (001) sheets. The water O atom accepts one N-H⋯O and two C-H⋯O inter-actio ...[more]

PMID: 22969656

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